CHLOROACETYL CHLORIDE

[zaners]

Anyone know some simple ways of making this? I know you can buy it but it's kinda restricted where I'm from

 

[G.Patton]

It is a lachrymator and has a strong, pungent odor, very unpleasant to work with. Stay away from synthesis of this. That's my recommendation if you wanna live long life =)

 

[FENTAMAS]

It's too boring to just live long life if you cannot cook some good shit for your area.
So if you want to see benzos you anyway need to get somehow chloroacetyl chloride.
The most accessible route is via monochloroacetic acid.
You also need Sulfur and TCCA or other chlorine source.

First step is to make crude S2Cl2. There are some good videos on youtube about it.
For example:

No need to bother with purifying it from SCl2 as it will be produced in later step anyway.

The second (and the last) step is to produce chloroacetyl chloride by combining all shit together and bubbling additional Cl2 via rxn mixture (with some catalytic amount of iron):

Example 1
1200 grams mono-chloracetic acid were mixed with 450 grams S2Cl2 and 2 grams iron filings, and chlorine passed in at a temperature of 50°- 60° C. When 2 lbs. 3 oz. (1105.6 g) chlorine had been absorbed, 100 grams more S2Cl2 were added, and 7 oz. (198.5 g) more chlorine.
The reaction product upon fractionation gave 1180 grams chloracetyl chloride, ClCHCOCl, and 213 grams lower boiling material containing only 1 per cent. SO2Cl2.
Yield 82 per cent. based upon chloracetic acid taken.

US1805162 - Preparation of aliphatic acid chlorides

This method is working, but likely you will get lower yield if you are not skilled and don't have efficient column.

 

[zaners]

It's too boring to just live long life if you cannot cook some good shit for your area.
So if you want to see benzos you anyway need to get somehow chloroacetyl chloride.
The most accessible route is via monochloroacetic acid.
You also need Sulfur and TCCA or other chlorine source.

First step is to make crude S2Cl2. There are some good videos on youtube about it.
For example:

No need to bother with purifying it from SCl2 as it will be produced in later step anyway.

The second (and the last) step is to produce chloroacetyl chloride by combining all shit together and bubbling additional Cl2 via rxn mixture (with some catalytic amount of iron):

US1805162 - Preparation of aliphatic acid chlorides

This method is working, but likely you will get lower yield if you are not skilled and don't have efficient column.

FENTAMASThanks man , I'll worry about my own health,it's like pulling teeth to get some info...I had already for some synthesis in some books but this helps as well